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MSDN XML Developer Center

XML tools from Microsoft including a set of interactive lessons that walk you through typical XML authoring and development tasks.

Visit free tutorial : MSDN XML Developer Center page
Most of the tutorials are either beginner or intermediate level, Just click to learn!

XML Schema Designer CTP1 Released!XML Schema Designer CTP1 Released!

The first Community Technology Preview (CTP) of the XML Schema Designer has been released. The XML Schema Designer is a graphical tool for working with XML Schemas. This CTP is targeted towards the Visual Studio developer who needs to interact with XML Schemas in the process of working on an application. It will not require an in-depth knowledge of the XML Schema spec and will be useable by both schema experts and novice users.

XML Notepad 2007XML Notepad 2007
XML Notepad 2007 provides a simple intuitive User Interface for browsing and editing XML documents. XML Notepad shows how to use some advanced features of System.XML in the .NET Framework 2.0.
XML Notepad 2007 DesignXML Notepad 2007 Design
This article introduces the new version of XML Notepad. The tool was first introduced in 1998 but has been unavailable for several years. This version leverages System.Xml and adds new features.